Organic Synthetic Reactions by Using Polynuclear Ruthenium Complexes

Organic reactions catalyzed by rhenium carbonyl complexes.

Investigation of Organic Complexes of Imidazolines Based on Synthetic Oxy- and Petroleum Acids as Corrosion Inhibitors

The mixture of Synthetic Petroleum Acids (SPA) and oxyacids (OSPA) have been synthesized on the basis of naphthenic-paraffinic hydrocarbons separated from 217-349°C fractions of Azerbaijan oils in the presence of the salts of Natural Petroleum Acids (NPA). The acid number of the obtained (SPA+OSPA) was 165 mgKOH/g, the yield was 40%. Imidazoline derivatives have been synthesized based on the mi...

Polynuclear Gold(I) Complexes of Mercaptocarboxylic Acids

Gold(I) Thiolates, (Benzylthiolato)gold(I) Complexes, Gold(I) Mercaptocarboxylates, Polynu­ clear Gold(I) Complexes In a search for air-stable and water-soluble mercapto compounds of gold with a high gold content, benzylthiol, a-mercapto-acetic acid, /3-mercapto-propionic acid, and thiosalicylic acid were converted into aurated sulfonium salts by treatment with reagents of the type [(R^PjAufiO*...

Dinuclear and Dendritic Polynuclear Ruthenium(II) and Osmium(II) Polypyridine Complexes: Electrochemistry at Very Positive Potentials in Liquid SO

The electrochemistry in liquid SO2 of RuII and OsII dendritic polynuclear complexes (two hexanuclear species, having as the core a bis-chelating ligand, and one decanuclear species, built around a metal core) has been performed together with that of several of their lower-nuclearity analogues (five dinuclear and one trinuclear species), which can be considered as components of the larger dendri...

Ruthenium Polyaminocarboxylate Complexes

taining polyaminocarboxylate (pac) ligands (Ru-pac) is of continuing interest. The donor character of the pac ligand is comparable with that of many biological enzymes which make use of the carboxylate and amine donors from amino acids to bind to a metal centre. The pac ligand can form very stable 1:1 (metal : ligand) complexes with ruthenium. Early studies (1-3), later confirmed by crystallogr...